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Scandium: the metal Mendeleev foresaw

Element 21: Scandium, the full story

Atomic number
21
Atomic mass
44.96
Shells
2, 8, 9, 2
Configuration
1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹
In the table
period 4, group 3 (IIIB), d-block
Kind
Transition metal
Valency
3 (Sc³⁺)
State at 25 °C
solid
Melts · boils
1,541 °C · 2,836 °C
Density
3.0 × as heavy as water
Known since
1879
A rough, sparkling silver-gray lump of metal crystals in a small glass vial
Very pure scandium crystals, 5 grams, about 2 cm across. Fresh scandium is silvery; in air it slowly takes on a yellowish or pinkish tinge. Photo: Hi-Res Images of Chemical Elements, CC BY 3.0

In 1871 a Russian chemist described a metal that no one had ever seen. He said how heavy its atoms would be and what its oxide would look like, and he gave it a name made from the Sanskrit word for one, eka (एक, the same word as in Nepali): eka-boron, “one place below boron”. Eight years later, a chemist in Sweden found it.

That metal is scandium. Today a little of it goes into some of the lightest, strongest aluminium in bicycle frames and aircraft. Here is its story.

The scandium atom

A scandium atom has 21 protons, so scandium’s atomic number is 21, and 21 electrons. Every scandium atom found in nature has 24 neutrons, so its mass number is 21 + 24 = 45.

You might expect the shells to be 2, 8, 8, 3: after calcium (2, 8, 8, 2), one more electron in the outer shell. But scandium is 2, 8, 9, 2. The 21st electron goes back into the M shell, which can hold 18 Grade 8: Bohr and Bury’s rule.

The reason shows in subshells Grade 10: The Aufbau principle. After 3p, the next subshell to fill is 4s, which has a little less energy than 3d. So potassium and calcium put their electrons in 4s, and then, with 4s full, scandium’s 21st electron goes into 3d, which belongs to the third shell:

1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹

KLMN21 p⁺24 nshells K, L, M, N: 2, 8, 9, 2energy1s2s2p3s3p4s3d3d¹: the 21stelectron (M: 9)4s² fills first (N: 2)3s, 3p full1s, 2s, 2p fulllose the 3 amber electrons: Sc³⁺, 2, 8, 8
Figure 1 A scandium atom. Left: the shell model, with 21 protons and 24 neutrons (scandium-45). Right: the subshells in order of energy; 4s fills first, then the 21st electron starts 3d.

How are scandium’s 21 electrons arranged in shells?

Pick an answer to see why.

Its place in the periodic table

  • Period 4, because its electrons are in four shells. It comes after calcium (20) and before titanium (22).
  • Group 3, called IIIB in the older naming many books use.
  • d-block, because its last electron goes into a d subshell. That makes scandium the first transition metal Grade 10: Metals: period 4’s ten transition metals, from scandium to zinc, are the elements that fill 3d.

Below scandium in group 3 is yttrium (39). Scandium, yttrium and the fifteen lanthanides together are called the rare-earth elements.

Its valency

In its compounds, scandium loses all three of its outer electrons, the two 4s and the one 3d, to become the ion Sc³⁺ Grade 9: Ions. Its valency is 3, and almost always only 3. That leaves Sc³⁺ with 2, 8, 8: exactly the electrons of the noble gas argon.

This makes scandium an odd transition metal. Most transition metals have a variable valency (iron is 2 or 3, copper 1 or 2) and colored compounds, because their ions still have d electrons Grade 9: Variable valency. Scandium’s ion has no d electrons left, so it has one valency, and its compounds are white or colorless, like those of aluminium.

Iron sulphate crystals are green, copper sulphate blue. Scandium sulphate is white. Why?

Pick an answer to see why.

How scandium was found and named

Mendeleev’s gap

When Dmitri Mendeleev arranged the elements by atomic weight in 1869, he noticed a jump between calcium (40) and titanium (48). Titanium did not behave like the elements of group III; it belonged with carbon and silicon in group IV. So he left a gap after calcium and said that an unknown element, with an atomic weight of about 44, belonged there Grade 10: Mendeleev’s periodic table. In 1871 he described it in detail and called it eka-boron, because it would sit one place below boron (and aluminium) in group III.

group Igroup IIgroup IIIgroup IVLi 7Be 9.4B 11C 12Na 23Mg 24Al 27.3Si 28K 39Ca 40? 44eka-boronTi 48Cu 63Zn 65? 68? 72? 44, eka-boron:scandium (1879)? 68: gallium (1875)? 72: germanium (1886)Mendeleev’s 1871 table, with his atomic weights. Each “?” is an element he said must exist.
Figure 2 A corner of Mendeleev’s table of 1871, with his atomic weights. The gap at 44 was eka-boron; the gaps at 68 and 72 were gallium and germanium, found in 1875 and 1886.

Nilson finds it

In 1879 the Swedish chemist Lars Fredrik Nilson, at the University of Uppsala, was separating the oxides of rare metals from two minerals found in Scandinavia, euxenite and gadolinite. From about 10 kilograms of mineral he got about 2 grams of a white oxide that no one had seen before. Its spectrum (the colors it gave out when heated in a flame or a spark) had lines no known element gave. He named the new element after Scandinavia (in Latin, Scandia): scandium, symbol Sc. Nepali books write it स्क्यान्डियम.

An old printed portrait, in an oval, of a man with glasses, gray hair and a short beard, wearing a dark jacket and bow tie
Figure 3 Lars Fredrik Nilson (1840–1899), who found scandium in 1879. Photo: Unknown author, Public domain

Nilson did not know about Mendeleev’s prediction. His colleague in Uppsala, Per Teodor Cleve, saw that scandium was exactly eka-boron, and wrote to tell Mendeleev.

Mendeleev’s eka-boron (1871) Scandium (found 1879)
place in the table group III, between calcium and titanium group 3, between calcium and titanium
atomic weight about 44 44.96
its oxide Eb₂O₃ Sc₂O₃
valency 3 3

After gallium (1875), scandium was the second of Mendeleev’s predicted elements to be found, and germanium the third (1886). Each one made chemists trust the periodic table more.

The pure metal was much harder to get. Scandium was first made as a metal only in 1937, by passing electricity through molten scandium chloride mixed with other salts, and the first half-kilogram of 99% pure scandium was made only in 1960.

Where scandium is found

In the universe. Scandium atoms are made in big stars and thrown out into space when the stars explode as supernovae (Getting the atoms out). It is more common in the Sun than on Earth: it is about the 23rd most common element in the Sun, but only about the 50th on Earth as a whole.

In the Earth’s crust. Scandium isn’t really rare: the crust holds about 20 grams per tonne, about as much as cobalt, and more than lead. But it is spread thinly through hundreds of different minerals and hardly ever gathered into an ore Grade 10: Ores. The only mineral that is mostly scandium, thortveitite, is found in a few places in Norway and Madagascar, and is too rare to mine.

A rock specimen with long, dark gray-green crystals rising from a pale pinkish base
Figure 4 Thortveitite, a scandium silicate, from southern Norway: the long, dark crystals. It can be almost half scandium oxide, but it is very rare. Photo: Ronald Werner, CC BY-SA 4.0

So nearly all scandium is a by-product, collected from the leftovers when other metals are extracted, mainly from nickel and titanium ores. In 2025 the whole world produced only about 80 tonnes of scandium oxide, most of it in China (USGS, 2026). Compare that with about 23 million tonnes of copper a year. Scandium metal costs about $5 a gram, far more than aluminium.

In Nepal and in your body. No scandium deposit is known in Nepal, and the body has no use for scandium.

What scandium is like

  • A silvery-white metal, fairly soft, that takes on a slightly yellow or pink tinge in air.
  • Light. Its density is 2.99 g/cm³, only a little more than aluminium’s, and less than titanium’s: it is the lightest of all the transition metals.
  • Melts at 1,541 °C, more than twice the temperature at which aluminium melts.
metal density (g/cm³) melting point (°C)
aluminium 2.70 660
scandium 2.99 1,541
titanium 4.5 1,668
iron 7.87 1,538

So scandium is almost as light as aluminium, but stands heat like iron. Pure scandium would be a wonderful material, if it weren’t so rare and costly.

How scandium reacts

Scandium is a reactive metal, much more like aluminium than like iron or copper.

  • With air. A piece slowly tarnishes. Thin shavings, heated, burn with a bright yellow flame, giving white scandium oxide:
    4Sc + 3O₂ → 2Sc₂O₃
  • With dilute acids, it gives a salt and hydrogen gas Grade 9: Metals and dilute acids:
    2Sc + 6HCl → 2ScCl₃ + 3H₂

Scandium’s oxide and hydroxide are amphoteric, like aluminium’s: they react with acids and with strong alkalis too. Its compounds are white or colorless, and in all of them scandium has a valency of 3: ScCl₃, Sc₂O₃, Sc₂(SO₄)₃.

Scandium in daily life

Aluminium with a pinch of scandium

Scandium’s main use is in alloys with aluminium Grade 8: Alloys. Adding only 0.1 to 0.5% of scandium makes aluminium much stronger. The scandium forms countless tiny particles inside the metal, which stop its crystals from growing big and its layers of atoms from sliding. It also keeps aluminium strong where it has been welded, which normally weakens it.

Such alloys have gone into parts of Russian fighter planes such as the MiG-29, and into sports goods where every gram counts: racing bicycle frames, baseball bats and tent poles.

A gray jet fighter with two tail fins and a red star, parked on a runway at an air show, with people walking around it
Figure 5 A MiG-29 fighter, one of the aircraft that used aluminium–scandium alloy in some parts. Photo: D. Miller, CC BY 2.0

Light like sunlight

A little scandium iodide in a powerful metal halide lamp makes its light very close to daylight. Such lamps have been used to light film and television studios and sports grounds at night, where colors must look true on camera.

Fuel cells

Fuel cells make electricity from a fuel, such as hydrogen, without burning it. In one kind, the solid oxide fuel cell, a ceramic made with scandium oxide lets the charged particles through at a lower temperature. According to the USGS, this is now one of scandium’s main uses.

Isotopes of scandium

Natural scandium has only one isotope, scandium-45, with 21 protons and 24 neutrons. That is why its atomic mass, 44.956, is so close to a whole number: there is no mixture to average Grade 9: Atomic mass. Only about twenty elements have just one natural isotope.

The radioactive scandium-46 (half-life 84 days) is used as a tracer: a little is added to oil in a refinery, or to the water or gas in an underground pipe, and detectors follow where it goes or find where a pipe leaks.

Scandium and your health

Scandium has no known job in any living thing. Scientists know little about how poisonous it is, so its compounds are handled with care, like other chemicals of unknown harm.

Surprising facts and records

  • A Sanskrit name in chemistry. Mendeleev used eka (one) and dvi (two) to name missing elements one or two places below a known one: rhenium was “dvi-manganese”. Some historians think he chose Sanskrit to honor the ancient Indian grammarian Pāṇini, who arranged the sounds of Sanskrit in a table of rows and columns.
  • The lightest transition metal. At 2.99 g/cm³, scandium is lighter than every other d-block metal.
  • More common in the Sun. About the 23rd most common element in the Sun, but only about the 50th on Earth.

In your science books

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